Superhydrophobic/superoleophilic cotton-oil absorbent: preparation and its application in oil/water separation

A superhydrophobic and superoleophilic oil sorbent was prepared by attaching SiO₂ particles onto a cotton fiber surface by a sol-gel method and subsequent octadecyltrichlorosilane modification. The surface formation was confirmed by Fourier transform infrared spectroscopy, scanning electron microscopy, and an observation of the water behavior on the cotton surface. The sorption capacity of the modified cotton in pure oil and in an oil/water mixture, the oil adsorption and the reusability were investigated. Compared with raw cotton, the as-prepared cotton absorbed different oils rapidly up to in excess of 25-75 g g^-1 its own weight, and the water adsorption was nearly 0 g g^-1. The modified cotton fiber could separate oil/water mixtures efficiently through a flowing system. After 10 cycles, the as-prepared cotton was still highly hydrophobic with a 6-times greater adsorption than raw cotton. By a simple modification, a low-cost, high-adsorption and environmentally friendly modified cotton could be prepared that can be considered a promising alternative to organic synthetic fibers to clean up oil spills.