Aqueous hybrids of amino-functionalized nanosilica and acrylamide-based polymer for enhanced oil recovery

Amino-functionalized nanosilica (ANS) was prepared using nanosilica (NS) and 3-aminopropyltriethoxysilane (APTES) aiming to reinforce the interaction between nanoparticles and polymer molecules. The copolymer of acrylamide, 2-acrylamido-2-methyl-1-propane sulfonic acid (PM), and four ANS samples with different NS to APTES ratios were synthesized. A series of nanoparticle/polymer hybrid systems were fabricated by introducing NS or ANS suspension into PM aqueous solution. The rheological properties and surface activities of these hybrid systems were studied in comparison with PM. The results indicate that the salt-tolerance and heat-resistance properties of PM solution were improved by the introduction of ANS particles. Moreover, the structures of ANS samples have a significant effect on the effectiveness of the nanoparticles due to the fact that the amine group density on the ANS surface can affect the strength of intermolecular interaction between nanoparticles and polymer molecules. Additionally, the better ability of the ANS sample with proper amine group density showed in reducing the oil/water interfacial tension over NS and other ANS samples made it a more promising chemical for enhancing oil recovery. The results from core flooding tests show that the PM/ANS system has the greatest oil recovery factor (16.30%), while the values for PM/NS and PM are 10.84% and 6.00%, respectively.