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Self-Healing Silsesquioxane-Based Materials.

Maria Nowacka¹, Anna Kowalewska¹

¹Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, Sienkiewicza 112, 90-363 Łódź, Poland.

|May 14, 2022

Summary

Polyhedral oligomeric silsesquioxanes (POSS) are key building blocks for advanced self-healing materials (SHM). These POSS-enhanced polymers offer dynamic bonding and enhanced macromolecular dynamics for versatile applications.

Keywords:

POSS hybrid materials polyhedral silsesquioxanes self-healing

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Area of Science:

Materials Science
Polymer Chemistry
Nanotechnology

Background:

Self-healing materials (SHM) aim to autonomously repair damage, extending material lifespan.
Polyhedral oligomeric silsesquioxanes (POSS) are nanoscale molecular building blocks with unique structural and chemical properties.
Integrating POSS into polymer matrices offers novel pathways to engineer advanced SHM.

Purpose of the Study:

To review the role of POSS as building blocks in the design and synthesis of self-healing materials.
To explore different strategies for incorporating POSS into polymer architectures for SHM.
To highlight the structure-property relationships governing POSS-based SHM performance.

Main Methods:

Review of synthetic approaches for incorporating POSS into polymer backbones or side chains.
Analysis of functionalization strategies to create dynamic bonds involving POSS.
Investigation of mechanisms by which POSS enhances polymer dynamics and self-healing capabilities.

Main Results:

POSS can be integrated as grafted side chains or main chain segments in polymers.
Functionalized POSS enables dynamic bond formation, acting as crosslinkers or mobility enhancers.
POSS incorporation leads to improved macromolecular dynamics via reversible cage release or aggregation-induced inclusions.

Conclusions:

POSS-based SHM exhibit unique properties due to tailored incorporation and dynamic bonding.
These materials demonstrate significant potential for applications including coatings, sealants, sensors, and biomedical uses.
POSS represent a versatile platform for developing next-generation self-healing polymer systems.