High Mechanical Properties of Stretching Oriented Poly(butylene succinate) with Two-Step Chain Extension

The structure, morphology, fracture toughness and flaw sensitivity length scale of chain-extended poly(butylene succinate) with various pre-stretch ratios were studied. PBS modification adopted from a multifunctional, commercially available chain-extension containing nine epoxy groups (ADR9) as the first step chain extension and hydroxyl addition modified dioxazoline (BOZ) as the second step. Time-temperature superposition (TTS) studies show that the viscosity increased sharply and the degree of molecular branching increased. Fourier transform infrared spectroscopy (FT-IR) confirm successful chain extension reactions. The orientation of the polymer in the pre-stretch state is such that spherulites deformation along the stretching direction was observed by polarized light optical microscopy (PLOM). The fracture toughness of sample (λ_fix = 5) is Γ ≈ 10⁶ J m^-2 and its critical flaw sensitivity length scale is Γ/W_c ≈ 0.01 m, approximately 5 times higher than PBS without chain-extension (Γ ≈ 2 × 10⁵ J m^-2 and Γ/W_c ≈ 0.002 m, respectively). The notch sensitivity of chain-extended PBS is significantly reduced, which is due to the orientation of spherulites more effectively preventing crack propagation. The principle can be generalized to other high toughness material systems.