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Structure and Dynamics of Supramolecular Polymers: Wait and See

Sandra M C Schoenmakers1, A J H Spiering1, Svenja Herziger2,3

  • 1Laboratory of Macromolecular and Organic Chemistry, Institute for Complex Molecular Systems, Eindhoven University of Technology, 5612 AZ Eindhoven, The Netherlands.

ACS Macro Letters
|May 16, 2022
PubMed
Summary

Chiral deuterium labeling in benzene-1,3,5-tricarboxamide (BTA) supramolecular polymers reveals time-dependent changes in helical structure and dynamics. Isotopic chirality unveils increased order and decreased dynamics over weeks.

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