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Updated: Sep 23, 2025

Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers
Published on: December 16, 2022
Solvent assisted photochemical formation of a new keto[3,3]paracyclophane
Ho Suk Shin1, Da Yoon Moon1, Sejin An1
1Department of Chemistry, Dongguk University, Seoul 04620, Korea. parkbs@dongguk.edu.
Abstract:
Photolysis of a phenacyl benzoate tethered with a phenol leads to a very efficient release of benzoic acid, which is suggested to occur by electron transfer and/or proton transfer from the remote phenol moiety to the triplet excited carbonyl. Photolysis of the compound in protic solvents forms a new keto[3,3]paracyclophane.
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