Preparation of structured biochar, its adsorption capacity of N and P and its characterization

Structured biochar (SC) was prepared by biochar from cattail-sludge mixture (CS) and high-density polyethylene (HDPE) and treated as an adsorbent, and the KH₂PO₄ and NH₄Cl solution were treated as adsorbates, to explore the adsorption capacity of phosphorus (P) and nitrogen (N) on SC in water. A single factor experimental method was employed to determine the optimal parameters for SC. The results showed that: 60% sizing amount, 5 N (cm²)^-1 molding pressure, 160 °C molding temperature and 95 min molding time were optimal parameters for SC preparation. The adsorption of P and N on SC conforms to the Langmuir model, with the distribution of adsorption sites on the surface tending to be even. The adsorption of P and N on SC is favorable and spontaneous, and the adsorption tends to be monolayer adsorption with a major role for chemical adsorption. The higher the temperature, the higher the adsorption capacity of P and N on SC is, and the affinity of SC with P is higher than that with N. The pseudo-second-order kinetic model for the adsorption of N and P by SC has a high degree of fit. The pH_pzc value of SC was 8.57. The hydrophobicity and stability of SC are rather high, with the surface particles closely bonded and increased roughness and pore diameter. The adsorption mechanism of P and N on SC can be attributed to pore filling, electrostatic attraction and hydrogen bonding. The results can provide a new technology for the resource utilization of cattails and sludge, a new idea for the recycling and reuse of biochar, and a basis for the selection of materials for the treatment of eutrophic water bodies.