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Related Concept Videos

Stereoisomerism02:52

Stereoisomerism

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Isomerism in Complexes
Isomers are different chemical species that have the same chemical formula.
Transition metal complexes often exist as geometric isomers, in which the same atoms are connected through the same types of bonds but with differences in their orientation in space. Coordination complexes with two different ligands in the cis and trans positions from a ligand of interest form isomers. For example, the octahedral [Co(NH3)4Cl2]+ ion has two isomers (Figure 1) In the cis...
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Stereoisomers02:32

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On the basis of mirror symmetry, stereoisomers of an organic molecule can be further classified into diastereomers and enantiomers. Diastereomers are stereoisomers that are not mirror images of each other. Substituted alkenes, such as the cis and trans isomers of 2-butene, are diastereomers, as these molecules exhibit different spatial orientations of their constituent atoms, are not mirror images of each other, and do not interconvert. Here, the interconversion is suppressed due to...
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Stereoisomerism of Cyclic Compounds02:33

Stereoisomerism of Cyclic Compounds

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In this lesson, we delve into the role of ring conformation and its stability, which determines the spatial arrangement and, consequently, the molecular symmetry and stereoisomerism of cyclic compounds. 1,2-Dimethylcyclohexane is used as a case study to evaluate the possible number of stereoisomers. Here, given the multiple (n = 2) chiral centers, there are 2n = 4 possible configurations that lack a plane of symmetry, as the ring skeleton exists in a non-planar chair conformation. In addition,...
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¹H NMR: Interpreting Distorted and Overlapping Signals01:02

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Spin systems where the difference in chemical shifts of the coupled nuclei is greater than ten times J are called first-order spin systems. These nuclei are weakly coupled, and their chemical shifts and coupling constant can generally be estimated from the well-separated signals in the spectrum.
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¹³C NMR: Distortionless Enhancement by Polarization Transfer (DEPT)01:20

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When proton-coupled carbon-13 spectra are simplified by a broadband proton decoupling technique, structural information about the coupled protons is lost. Distortionless enhancement by polarization transfer (DEPT) is a technique that provides information on the number of hydrogens attached to each carbon in a molecule. While the DEPT experiment utilizes complex pulse sequences, the pulse delay and flip angle are specifically manipulated. The resulting signals have different phases depending on...
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¹H NMR Chemical Shift Equivalence: Enantiotopic and Diastereotopic Protons00:58

¹H NMR Chemical Shift Equivalence: Enantiotopic and Diastereotopic Protons

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Replacing each alpha-hydrogen in chloroethane by bromine (or a different functional group) yields a pair of enantiomers. Such protons are called prochiral or enantiotopic and are related by a mirror plane. Enantiotopic protons are chemically equivalent in an achiral environment. Because most proton NMR spectra are recorded using achiral solvents, enantiotopic hydrogens yield a single signal.
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A Psychophysics Paradigm for the Collection and Analysis of Similarity Judgments
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JPEG Steganography With Content Similarity Evaluation.

Zichi Wang, Guorui Feng, Zhenxing Qian

    IEEE Transactions on Cybernetics
    |May 17, 2022
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    Summary
    This summary is machine-generated.

    This study introduces a novel JPEG steganography method leveraging content similarity. By incorporating block and channel similarities into the distortion function, it enhances undetectability against steganalysis.

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    Area of Science:

    • Digital Image Processing
    • Information Security
    • Computer Vision

    Background:

    • Modern steganalysis utilizes image content similarity, a property often overlooked by existing JPEG steganography techniques.
    • Current JPEG steganographic methods primarily focus on content complexity, neglecting the potential of content similarity for improved security.

    Purpose of the Study:

    • To enhance the undetectability of JPEG steganography by investigating and utilizing image content similarity.
    • To develop a novel distortion function that incorporates content similarity for more robust secret data embedding.

    Main Methods:

    • A new distortion function is designed by updating initial embedding costs of DCT coefficients with DCT block and channel similarities.
    • Syndrome Trellis Coding (STC) is employed to embed secret data with minimal distortion using the final distortion function.
    • The method processes quantized DCT coefficients and updates embedding costs based on spatial and channel-wise similarities.

    Main Results:

    • The proposed JPEG steganography scheme demonstrates superior undetectability compared to existing state-of-the-art methods.
    • Experimental results validate the effectiveness of incorporating content similarity into the distortion function.
    • The method successfully embeds secret data while maintaining a high degree of imperceptibility.

    Conclusions:

    • Leveraging content similarity, specifically DCT block and channel similarities, significantly improves JPEG steganography undetectability.
    • The developed distortion function and embedding strategy offer a more secure approach to hiding data in JPEG images.
    • This research advances the field of steganalysis by providing a method that is harder to detect.