Related Experiment Video
Updated: Sep 22, 2025

Synthesis of Cyclic Polymers and Characterization of Their Diffusive Motion in the Melt State at the Single Molecule Level
Published on: September 26, 2016
High Performance and Multipurpose Triarylamine-Enchained Semifluorinated Polymers
Daniel K Dei, Benjamin R Lund, Jingbo Wu
1Intel Corporation, Chandler, Arizona 85226, United States.
Abstract:
Transparent, film-forming fluorinated arylene vinylene ether (FAVE) polymers with enchained triarylamine (TAA) moieties were prepared and characterized. Control over fluoro-olefin content within the backbone, as a function of base, was confirmed and postpolymerization dehydrofluorination was shown to increase fluoroolefin content from 5 to 31 mol %. Thermal cross-linking was found to occur approximately 100 °C lower than in traditional FAVE polymers (ca. 160 °C). Electrochemical analysis demonstrated the enchained TAA retained its established electrochemical character. The latent reactivity of the TAA was explored via electrophilic aromatic substitution and formylation reactions toward precise functionalization for specific electro-optic applications and others.
More Related Videos
Related Concept Videos
Olefin Metathesis Polymerization: Acyclic Diene Metathesis (ADMET)
Similar to cross-metathesis, ADMET also involves the formation of metallacyclobutane intermediate by [2+2] cycloaddition of one of the double bonds of a terminal diene with...
Anionic Chain-Growth Polymerization: Overview
Olefin Metathesis Polymerization: Overview
Ruthenium-based Grubbs catalyst is the most commonly used catalyst for olefin metathesis polymerization. Grubbs catalyst consists...
Characteristics and Nomenclature of Homopolymers
Ziegler–Natta Chain-Growth Polymerization: Overview
Polymer Classification: Architecture

