Rapid and enhanced adsorptive mitigation of groundwater fluoride by Mg(OH)₂ nanoflakes

Fluoride is one of the most abundant anions in groundwater, posing a significant threat to the safe drinking water supply worldwide. Fluoride contamination in drinking water at levels greater than 1.5 mg L^-1 causes a variety of serious health problems. To address this problem, the current study deals with the synthesis of Mg(OH)₂ nanoflakes by a facile and simple hydrothermal method in the absence of any added template. The sizes of these nanoflakes are in the range of 90 to 200 nm. These nanoflakes are pure and crystalline, possessing hexagonal phase structures. The surface areas of Mg(OH)₂ nanoflakes are varying from 75.8 to 108.1 m² g^-1. These Mg(OH)₂ nanoflakes exhibit excellent adsorption performance for fluoride over a pH range of 2.0 to 9.0 with a maximum Langmuir adsorption capacity of 3129 mg g^-1 at pH 7.0 at 313 K which is the highest for such kind of adsorbent reported so far. The adsorption process is spontaneous and endothermic which primarily follows pseudo-second-order kinetics. The adsorbent is effective in the presence of co-existing anions and is reusable up to the fifth cycle with a minimal loss of adsorption performance. The nanoflakes can effectively remove highly concentrated groundwater fluoride to a permissible limit within a short time which increases the versatility of using these nanoflakes for practical applications.