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Published on: January 23, 2018
Role of Ions in Hydrogels with an Ionic Seebeck Coefficient of 52.9 mV K-1
Yongjie He1, Qi Zhang1, Hanlin Cheng2
1MOE Key Laboratory of Low-grade Energy Utilization Technologies and Systems, CQU-NUS Renewable Energy Materials & Devices Joint Laboratory, School of Energy & Power Engineering, Chongqing University, Chongqing 400044, China.
Abstract:
Ionic thermoelectric (i-TE) material with mobile ions as charge carriers has the potential to generate large thermal voltages at low operating temperatures. This study highlights the role of ions in i-TE hydrogels employing a poly(vinyl alcohol) (PVA) polymer matrix and a number of ion providers, e.g., KOH, KNO3, KCl, KBr, NaI, KI, and CsI. The relationship between the intrinsic physical parameters of the ion and the thermoelectric performance is established, indicating the ability to influence the hydrogen bond by the ion is a crucial factor. Among these i-TE hydrogels, the PVA/CsI hydrogel exhibits the largest ionic Seebeck coefficient, reaching 52.9 mV K-1, which is the largest of all i-TE materials reported to date. In addition, our work demonstrates the influence of ions on polymer configuration and provides an avenue for ion selection in the Soret effect in ionic thermoelectrics.
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