Solely 3-Coordinated Organic-Inorganic Hybrid Copper(I) Halide: Hexagonal Channel Structure, Turn-On Response to...

Herein, we report a novel organic-inorganic hybrid Cu^I halide PyCs₃Cu₂Br₆ (Py: pyridinium), where pyridinium and cesium ions coexist. We successfully develop a novel strategy for fabricating turn-on responsive materials. PyCs₃Cu₂Br₆ has a higher single-crystal symmetry (no. 191) than its all-inorganic counterpart Cs₃Cu₂Br₅ (no. 62), and the incorporation of organic pyridinium varied the coordination environment of Cu^I. PyCs₃Cu₂Br₆ formed a triangle planar structure with solely 3-coordinated Cu^I ions, which quenched its luminescence. However, PyCs₃Cu₂Br₆ presented a hexagonal channel structure, which enabled it with turn-on response upon mechanical force, heat, moisture, and amine vapor. Such structure offered channels for active molecules to diffuse and interact with pyridiniums, leading to the stimuli-triggered phase change to highly emissive Cs₃Cu₂Br₅. To our best knowledge, for the first time, we discover a novel 3-coordinated organic-inorganic hybrid Cu^I halide with turn-on response to external stimuli. We believe that our study will contribute to expanding the landscape of smart stimulus-responsive materials and lay the foundation for their wide applications.