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Updated: Sep 22, 2025

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Chemical Gardens as Flow-through Reactors Simulating Natural Hydrothermal Systems
Published on: November 18, 2015
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Archimedean Spirals Form at Low Flow Rates in Confined Chemical Gardens
Luis A M Rocha1, Lewis Thorne1, Jasper J Wong1
1Department of Chemical Engineering and Biotechnology, University of Cambridge, Cambridge CB2 3RA, U.K.
Langmuir : the ACS Journal of Surfaces and Colloids
|May 20, 2022
Summary
Researchers studied confined chemical garden patterns, observing spiral formation from cobalt chloride and sodium silicate. Mathematical modeling helped estimate precipitate density and membrane permeability.
Area of Science:
- Materials Science
- Chemical Engineering
- Fluid Dynamics
Background:
- Chemical gardens exhibit complex pattern formation.
- Confined geometries influence precipitate growth dynamics.
- Previous studies explored filament formation in chemical gardens.
Purpose of the Study:
- To investigate the formation of confined chemical garden patterns.
- To model the growth dynamics of spiral structures.
- To determine key physical parameters of the precipitate.
Main Methods:
- Utilized a Hele-Shaw cell for confined experiments.
- Injected cobalt chloride solution into sodium silicate.
- Developed mathematical models to simulate growth.
- Estimated precipitate density and membrane permeability.
Main Results:
- Observed the formation of Archimedean spiral structures.
- Characterized precipitate growth as filament wrapping around a "candy floss" core.
- Quantified effective precipitate density.
- Calculated membrane permeability.
Conclusions:
- Successfully described and modeled confined chemical garden spiral formation.
- Provided insights into the physical properties governing precipitate growth.
- Contributed to the understanding of pattern formation in confined reactive systems.
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