Cu₂O induced Au nanochains for highly sensitive dual-mode detection of hydrogen sulfide

Colorimetric and chemoresistive gas sensing methods have aroused great interest in H₂S monitoring due to their unique merits of naked-eye readout, and highly sensitive and rapid detection. However, combining these two methods for gas detection, especially utilizing one material as their common sensing material is a grand challenge because they are inconsistent in sensing mechanism. Taking advantage of the strong chemical affinity of Cu₂O for H₂S and the excellent performance of localized surface plasmon resonance (LSPR) of Au nanoparticles (NPs) in the visible regions and its ability as a noble metal to enhance gas sensing property, the Cu₂O-Au nanochains (NCs) were prepared for dual-mode detection of H₂S gas. The Cu₂O-Au chemoresistive gas sensor shows a 5-fold higher response than Cu₂O sensor at room temperature with a low detection limit of 10 ppb. Such good performance is attributed to the spillover effect and catalytic activity of Au NPs, and the enhanced H₂S adsorption after Au loading as revealed by density functional theory calculation. Test strips containing Cu₂O-Au produced for gaseous H₂S detection show superior color gradient changes (blue, yellow, and brown). Finally, the practicability of the method was validated by real-time monitoring H₂S released from cell culture.