TiO₂/AgO composites by one step photo reduction technique as electron transport layers (ETL) for dye-sensitized solar...

Dye-sensitized solar cell's electron transport layer is responsible for transporting photo-generated electrons to the outer circuit. Utilizing localized surface plasmon resonance (SPR), light absorption could be enhanced to a greater degree, which can drive dye molecules to excited state more effectively than far-field light. In this work, TiO₂ nanoparticles were prepared by solvothermal method, and Ag nanoparticles were decorated over TiO₂ surface through photodeposition method. XRD data of the TiO₂ sample exhibits anatase phase and in the Ag nanoparticle decorated TiO₂ sample, peaks corresponding to (111) planes of Ag was observed. UV-Vis absorption analysis of the TiO₂ and Ag decorated TiO₂ samples showed absorption in the UV region for the TiO_2, and the SPR effect was detected for the Ag deposited TiO₂ samples. Ag nanoparticles decorated over TiO₂ was observed to be spherical in shape through the images from transmission electron microscope. Presence of both Ag and AgO in the prepared sample was revealed through the data from X-ray photoelectron spectroscopy. The prepared material was used as photoanodes in the construction of the DSSCs, and their performance was evaluated.