Removal of p-Nitrophenol from simulated sewage using steel slag: Capability and mechanism

The steel slag was investigated for the removal of p-nitrophenol (4-NP) from simulated sewage by batch adsorption and fixed-bed column absorption experiments. The results showed that the maximum adsorption capacity was 109.66 mg/g at 298 K, pH of 7, initial concentration 100 mg/L, and dose 0.8 g/L. The adsorption process fitted the Langmuir isothermal adsorption model and followed pseudo-second-order kinetic models, the activation energy of adsorption (Ea) was 10.78 kJ/mol, which indicated that the adsorption was single-molecule layer physical adsorption. The regeneration efficiency was still maintained at 84.20% after five adsorption-desorption cycles. The column adsorption experiments showed that the adsorption capacity of the Thomas model reached 13.69 mg/g and the semi-penetrating time of the Yoon-Nelson model was 205 min at 298 K. Fe₃O₄ was identified as the main adsorption site by adsorption energy calculation, XRD and XPS analysis. The FT-IR, Zeta potential, and ionic strength analysis indicated that the adsorption mechanism was hydrogen bonding interaction and electrostatic interaction. This work proved that steel slag could be utilized as a potential adsorbent for phenol-containing wastewater treatment.