Enhancing hydroxyl radical production from cathodic ozone reduction during the ozone-electrolysis process with...

In this study, a flow-through ozone-electrolysis (O₃-electrolysis) process was developed by combining ozonation with an electrolysis using a porous reactive electrochemical membrane (REM) cathode. Due to the convection-enhanced mass transport and fast radial diffusion inside the small pores of REM cathodes, the rate of cathodic O₃ reduction to ozonide radicals (O₃^•-) was significantly enhanced, while the further cathodic O₃^•- reduction to oxygen was inhibited during the flow-through O₃-electrolysis process compared to the conventional mixed-tank O₃-electrolysis process. Consequently, more hydroxyl radicals (•OH) were formed from O₃^•- decay in water during the flow-through O₃-electrolysis process than the mixed-tank O₃-electrolysis process. Corresponding to the higher •OH yields from cathodic O₃ reduction, the flow-through O₃-electrolysis process substantially enhanced the abatement kinetics and efficiency of para-benzoic acid (pCBA, a model compound of ozone-resistant micropollutant) in a groundwater than conventional ozonation and the mixed-tank O₃-electrolysis process. These results suggest that the flow-through O₃-electrolysis process may provide a competitive treatment technology for micropollutant abatement in water treatment.