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Updated: Sep 22, 2025

Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers
Published on: December 16, 2022
Minimal Surfaces on Unconcatenated Polymer Rings in Melt
Jan Smrek1, Alexander Y Grosberg1
1Center for Soft Matter Research and Department of Physics, New York University, New York, New York 10003, United States.
Abstract:
In order to quantify the effect of mutual threading on conformations and dynamics of unconcatenated and unknotted rings in the melt we computationally examine their minimal surfaces. We found a linear scaling of the surface area with the ring length. Minimal surfaces allow for an unambiguous algorithmic definition of mutual threading between rings. Based on it, we found that, although ring threading is frequent, majority of cases correspond to short loops. These findings explain why approximate theories that neglect threading are so unexpectedly successful despite having no small parameter justification. We also examine threading dynamics and identify the threading order parameter that reflects the ring diffusivity.
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