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Updated: Sep 22, 2025

Anionic Polymerization of an Amphiphilic Copolymer for Preparation of Block Copolymer Micelles Stabilized by π-π Stacking Interactions
Published on: October 10, 2016
100th Anniversary of Macromolecular Science Viewpoint: Block Copolymers with Tethered Acid Groups: Challenges and
Sejong Kang1, Moon Jeong Park1
1Department of Chemistry, Pohang University of Science and Technology (POSTECH), Pohang, Korea 790-784.
Abstract:
Scientific research on advanced polymer electrolytes has led to the emergence of all-solid-state energy storage/transfer systems. Early research began with acid-tethered polymers half a century ago, and research interest has gradually shifted to high-precision polymers with controllable acid functional groups and nanoscale morphologies. Consequently, various self-assembled acid-tethered block polymer morphologies have been produced. Their ion properties are profoundly affected by the multiscale intermolecular interactions in confinements. The creation of hierarchically organized ion/dipole arrangements inside the block copolymer nanostructures has been highlighted as a future method for developing advanced single-ion polymers with decoupled ion dynamics and polymer chain relaxation. Several emerging practical applications of the acid-tethered block copolymers have been explored to draw attention to the challenges and opportunities in developing state-of-the-art electrochemical systems.
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