Photocatalytic nanohybrid membranes for highly efficient wastewater treatment: A comprehensive review

Wastewater is inevitably generated from human activities as part of the life cycle chain that potentially damages the environment. The integration of photocatalytic reaction and membrane separation for wastewater treatment has gained great attention in recent studies. However, there are still many technical limitations for its application such as toxic metal release, catalyst deactivation, fouling/biofouling, polymer disintegration, and separation performance decline. Different types, combinations, and modifications of photocatalysts material combined with membranes such as semiconductor metal oxides, binary/ternary hybrid metal oxides, elemental doped semiconductors, and metal-organic frameworks (MOFs) for improving the performance and compatibility are presented and discussed. The strategies of incorporating photocatalysts into membrane matrix for pursuing the most stable membrane integrity, high photocatalytic efficiency, and excellent perm-selectivity performance in the very recent studies were discussed. This review also outlines the performance enhancement of photocatalytic membranes (PMs) in wastewater treatment and its potential for water reclamation. Photocatalysts enhanced membrane separation by inducing anti-fouling and self-cleaning properties as well as antibacterial activity. Based on the reviewed study, PMs are possible to achieve complete removal of emerging contaminants and ∼99% reduction of bacterial colony that leading on the zero liquid discharge (ZLD). However, the intensive exposure of photo-induced radicals potentially damages the polymeric membrane. Therefore, future studies should be focused on fabricating chemically stable host-membrane material. Moreover, the light source and the membrane module design for the practical application by considering the hydrodynamic and cost-efficiency should be a concern for technology diffusion to the industrial-scale application.