Unique On-Site Spinning Sampling of Highly Water-Soluble Organics Using Functionalized Monolithic Sorbents

Water utilities encounter unpredictable odor issues that cannot be explained by routine water parameters during spring runoff, even in the summer and fall. Highly water-soluble organics (e.g., amino acids and saccharides) have been reported to form odorous disinfection byproducts during disinfection, but the lack of simple and practical on-site sampling techniques hampers their routine monitoring at trace levels in source water. Therefore, we have created two functionalized nested-in-sponge silica monoliths (NiS-SMs) using a one-pot synthesis method and demonstrated their application for extracting highly soluble organics in water. The NiS-SMs functionalized with the sulfonic group and phenylboronic moiety selectively extracted amino acids and monosaccharides, respectively. We further developed a spinning sampling technique using the composites and evaluated its robust performance under varying water conditions. The spinning sampling coupled to high-performance liquid chromatography tandem mass spectrometry analysis provided limits of detection for amino acids at 0.038-0.092 ng L^-1 and monosaccharides at 0.036-0.14 ng L^-1. Using the pre-equilibrium sampling-rate calibration, we demonstrated the applicability of the spinning sampling technique for on-site sampling and monitoring of amino acids and monosaccharides in river water. The new composite materials and rapid on-site sampling technique are unique and efficient tools for monitoring highly soluble organics in water sources.