Fabrication of Polyacrylonitrile UF Membranes by VIPS Method with Acetone as Co-Solvent

For the first time, a systematic study was carried out of the replacement of the low-volatility solvents N-methyl-2-pyrrolidone (NMP) or dimethylsulfoxide (DMSO) with the high-volatility solvent acetone in the casting solution of polyacrylonitrile (PAN). The effect of acetone's presence in the casting solution on the performance of ultrafiltration membranes fabricated via vapor-induced phase separation (VIPS) was investigated. It was possible to replace 40% of NMP and 50% of DMSO with acetone, which resulted in the reduction of the casting solution viscosity from 70.6 down to 41.3 Pa∙s (20% PAN, NMP), and from 68.3 down to 20.6 Pa∙s (20% PAN, DMSO). It was found that 20 min of exposure to water vapor (relative humidity-85%) was sufficient to govern the phase separation, which was mainly induced by the water vapor. Regardless of the casting solution composition (15 or 20% PAN; DMSO or NMP), all membranes formed via VIPS possessed a sponge-like porous structure. The addition of acetone to the casting solution allowed the reduction of the transport pore size from 35-48 down to 8.5-25.6, depending on the casting solution composition. By varying the acetone content at constant polymer concentration, it was possible to decrease the molecular weight cut-off (MWCO) from 69 to 10 kg/mol. Membranes prepared from 20% PAN solution in an acetone/DMSO mixture had the lowest MWCO of 10 kg/mol with a water permeance of 5.1 L/(m²·h·bar).