Constructing Co₃O₄/La₂Ti₂O₇ p-n Heterojunction for the Enhancement of Photocatalytic Hydrogen Evolution

Layered perovskite-type semiconductor La₂Ti₂O₇ has attracted lots of attention in photocatalytic hydrogen evolution, due to the suitable energy band position for water splitting, high specific surface area, and excellent physicochemical stability. However, the narrow light absorption range and the low separation efficiency of photogenerated carriers limit its photocatalytic activity. Herein, plate-like La₂Ti₂O₇ with uniform crystal morphology was synthesized in molten NaCl salt. A p-n heterojunction was then constructed through the in situ hydrothermal growth of p-type Co₃O₄ nanoparticles on the surface of n-type plate-like La₂Ti₂O₇. The effects of Co₃O₄ loading on photocatalytic hydrogen evolution performance were investigated in detail. The results demonstrate that composite Co₃O₄/La₂Ti₂O₇ possesses much better photocatalytic activity than the pure component. The composite photocatalyst with 1 wt% Co₃O₄ exhibits the highest hydrogen evolution rate of 79.73 μmol·g^-1·h^-1 and a good cycling stability. The photoelectrochemistry characterizations illustrate that the improvement of photocatalytic activity is mainly attributed to both the enhanced light absorption from the Co₃O₄ ornament and the rapid separation of photogenerated electron-hole pairs driven by the built-in electric field close to the p-n heterojunction. The results may provide further insights into the design of high-efficiency La₂Ti₂O₇-based heterojunctions for photocatalytic hydrogen evolution.