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A Polyaniline-based Sensor of Nucleic Acids
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Core/Shell Pigments with Polyaniline Shell: Optical and Physical-Technical Properties.

Tatyana A Pugacheva1, Georgiy V Malkov1, Alexander A Ilyin2

  • 1Institute for Problems of Chemical Physics of the Russian Academy of Sciences (IPCP RAS), Academician Semenov Avenue 1, 142432 Chernogolovka, Russia.

Polymers
|May 28, 2022
PubMed
Summary

Core/shell pigments combine anti-corrosion and barrier effects for low-toxicity, high-protection coatings. Their optical and absorption properties are optimized with specific polyaniline (PANi) content and core materials like kaolin and talc.

Keywords:
core/shell pigmentsdopinginorganic fillersoptical propertiespolyaniline

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Area of Science:

  • Materials Science
  • Corrosion Science

Background:

  • Core/shell pigments offer combined anti-corrosion and barrier properties.
  • They present an opportunity for low-toxicity, high-protective coatings in paints and varnishes.

Purpose of the Study:

  • To comprehensively study the properties of core/shell pigments.
  • To evaluate the impact of polyaniline (PANi) content on pigment characteristics.

Main Methods:

  • Investigated core/shell pigments with varying PANi content (5-50 wt.%) using sulfuric and phosphoric acids as dopants.
  • Assessed pigment properties including hiding power, blackness, and oil absorption.
  • Compared performance against pure PANi and black-iron-oxide pigments.

Main Results:

  • Hiding power approaches pure PANi at 50 wt.% PANi.
  • Blackness is constant around 35 above 10 wt.% PANi, with kaolin-based pigments showing lower blackness at 5 wt.%.
  • A 20 wt.% PANi pigment is optically equivalent to black-iron-oxide; higher PANi increases oil absorption.

Conclusions:

  • Core/shell pigments demonstrate tunable optical and protective properties.
  • Energy-efficient dispersion is achieved with kaolin and talc cores.
  • These pigments show promise for advanced anti-corrosion applications.