Durability and Service Life Prediction of Fluorocarbon Elastomer under Thermal Environments

This study investigated the service life prediction of fluorocarbon elastomers that are used in automotive vapor fuel hoses under thermal environments. The changes in mechanical properties such as the tensile strength, elongation, compression set (CS), and hardness according to thermal aging were investigated for two types of ternary fluoroelastomers. Destructive tests of the tensile strength and elongation showed large variations in the mechanical properties under the same condition because there is no continuity of samples. In contrast, nondestructive tests of the CS and hardness showed little variations in the mechanical properties under the same condition. The elongation, CS, and hardness were selected as the physical parameters for service life prediction as they showed a tendency according to the aging temperature, which is an accelerating factor. The effective activation energy derived using each physical parameter was 74.91-159.6 kJ mol^-1, and the service life was 17.8-140 × 10³ h based on B₁₀. In this study, hardness, which has a small deviation between samples, is considered appropriate as mechanical parameter for predicting the service lifetime.