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Updated: Sep 21, 2025

Studying Large Amplitude Oscillatory Shear Response of Soft Materials
Published on: April 25, 2019
Large Amplitude Oscillatory Shear Induces Crystal Chain Orientation in Velocity Gradient Direction
K Sreenivas1, Guruswamy Kumaraswamy1
1Complex Fluids and Polymer Engineering, CSIR-National Chemical Laboratory, India.
Abstract:
Imposition of large amplitude oscillatory shear (LAOS) on crystallizing polymer melts results in lamellar orientation in the shear gradient direction, in contrast to the flow-orientation observed for steady shear. LAOS enhances the formation of plate-like nuclei and orients their normals in the gradient direction. An Arrhenius temperature dependence (with activation energy ≈ 226 kJ/mol) characterizes the relaxation of crystal orientation with annealing.
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