Multicolor Mechanochromic Polymer Blends That Can Discriminate between Stretching and Grinding

Mechanochromic polymers, which react to mechanical force by changing color, are expected to find applications in smart materials such as damage sensors. Although numerous types of mechanochromic polymers have been reported so far, developing mechanochromic polymers that can recognize different mechanical stimuli remains a formidable challenge. Materials that not only change their color in response to a mechanical stimulus but also detect its nature should be of great importance for practical applications. In this paper, we report our preliminary findings on multicolor mechanochromic polymer blends that can discriminate between two different mechanical stimuli, i.e., stretching and grinding, by simply blending two mechanochromic polymers with different architectures. The rational design and blending of two mechanochromic polymers with radical-type mechanochromophores embedded separately in positions adjacent to soft or hard domains made it possible to achieve multicolor mechanochromism in response to different stimuli. Electron paramagnetic resonance and solid-state UV-vis measurements supported the mechanism proposed for this discrimination.