Long-Lasting Self-Healing Surface Dewettability through the Rapid Regeneration of Surface Morphologies

The development of self-healing systems for artificial superhydrophobic materials/surfaces based on the reconstruction of surface topologies rather than chemical makeup has been much less established. In this article, we report for the first time a simple and straightforward method for self-repairing surface dewettability over a long period of time by rapidly regenerating surface microstructures. We selected paraffin wax as a matrix for methyltrichlorosilane (MTCS) having strong reactivity with moisture/water and simply mixed them. When the as-prepared MTCS-loaded paraffin wax surfaces were exposed to air for a few hours, they spontaneously became highly hydrophobic with water contact angles of about 150° due to the formation of disordered surface microstructures. The use of paraffin wax with a few angstrom-scale space as a matrix was found to be more effective than the use of poly(dimethylsiloxane) with nanometer-size porosity in preventing both evaporation and degradation of MTCS's chemical reactivity for a long period. Therefore, for about 1 month, even after the surface microstructures were completely destroyed, surface dewettability could be self-repaired by rapidly regenerating surface morphologies. In addition, chemical damage by UV/ozone exposure could also be repeatably self-healed by the reconstruction of surface chemical makeup. We thus expect that this simple approach could provide future insights to impart the self-healing ability of manmade superhydrophobic materials/surfaces against chemical and physical damages.