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Quantifying MCPA load pathways at catchment scale using high temporal resolution data.

Kevin Atcheson1, Per-Erik Mellander2, Rachel Cassidy3

  • 1School of Geography and Environmental Sciences, Ulster University, Coleraine, UK.

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MCPA herbicide is highly mobile in water, with most loss occurring during storm events via surface flow. Understanding these pathways is key for effective water quality management.

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Area of Science:

  • Environmental Chemistry
  • Hydrology
  • Water Resource Management

Background:

  • Detection of the herbicide MCPA in drinking water sources is a growing concern due to its mobility and unknown catchment-scale transport.
  • Understanding MCPA's hydrological pathways is crucial for effective mitigation and monitoring of water quality.

Purpose of the Study:

  • To investigate MCPA transport pathways in a river catchment during the herbicide spraying season.
  • To quantify MCPA loads and differentiate contributions from various hydrological pathways.

Main Methods:

  • Collected river discharge and MCPA concentration data over a 7-month spraying season.
  • Utilized continuous and hourly sampling during storm events.
  • Applied pathway separation techniques to apportion MCPA loads into event and baseflow components.

Main Results:

  • 85.2 kg of MCPA was exported from the catchment over 7 months.
  • 87.7% of MCPA load was transported via event flow, with 72.0% via surface-dominated (quickflow) pathways.
  • Approximately 12% of MCPA was transported via deep baseflows, indicating persistence.

Conclusions:

  • MCPA loss from catchments is predominantly an acute, storm-dependent process.
  • Reducing herbicide use and disconnecting surface pathways are key mitigation strategies.
  • High temporal resolution monitoring is essential for assessing mitigation effectiveness.