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Redox-Switchable Complexes Based on Nanographene-NHCs
César Ruiz-Zambrana1, Rajeev K Dubey2, Macarena Poyatos1
1Institute of Advanced Materials (INAM). Centro de Innovación en Química Avanzada (ORFEO-CINQA)., Universitat Jaume I., Av. Vicente Sos Baynat s/n., Castellón., 12071, Spain.
Abstract:
A series of rhodium and iridium complexes with a N-heterocyclic carbene (NHC) ligand decorated with a perylene-diimide-pyrene moiety are described. Electrochemical studies reveal that the complexes can undergo two successive one-electron reduction events, associated to the reduction of the PDI moiety attached to the NHC ligand. The reduction of the ligand produces a significant increase on its electron-donating character, as observed from the infrared spectroelectrochemical studies. The rhodium complex was tested in the [3+2] cycloaddition of diphenylcyclopropenone and methylphenylacetylene, where it displayed a redox-switchable behavior. The neutral complex showed moderate activity, which was suppressed when the catalyst was reduced.
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