Schiff base compounds as fluorimetric pH sensor: a review

With the recent progress of biological and environmental research, detection of pH values has become one of the most indispensable requirements. To determine the pH values of a certain medium, organic Schiff base compounds and their derivatives have been observed to play pivotal roles because of their smooth synthetic roots, easily tuneable structural architecture, non-destructive signals of emission, visually differentiable colour generation and capability of real sample analysis. Therefore with the revolutionary upgradation of wavelength radiometric techniques, the construction of molecular structures which can exhibit dual emission and absorption characteristics and which can be regulated by the change in pH values, has been a stimulating challenge. Generally a pH sensor molecule has a chromophoric or fluorophoric portion. Normally heteroatoms attached to these chromophore units either get protonated or deprotonated in acidic or basic media which gives rise to changes in absorption and emission properties of the molecule.