Related Experiment Video

Updated: Sep 21, 2025

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
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Published on: June 21, 2017

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Computational insights into strain-increase allylborations for alkylidenecyclopropanes

Lingfei Hu1, Han Gao1, Yanlei Hu1

  • 1School of Chemistry and Chemical Engineering, Key Laboratory of Colloid and Interface Chemistry, Ministry of Education, Shandong University, Jinan, Shandong, 250100, China. ganglu@sdu.edu.cn.

Chemical Communications (Cambridge, England)
|June 1, 2022
PubMed
Summary

Computational studies revealed that increasing boron center acidity enhances strain-increase allylborations. This improvement overcomes weak electronic interactions and steric hindrance, boosting reactivity in organic synthesis.

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