Efficient removal of the antibiotic Cefixime on Mg_0.3Zn_0.7O under solar light: kinetic and mechanism studies

The heterogeneous photocatalysis is known to provide significant degradation and mineralization of emerging contaminants including antibiotics. For this, nanosized Mg_0.3Zn_0.7O (MZO) was prepared by nitrate route to be used as photocatalyst. The single-phase was confirmed by X-ray diffraction with a crystallite size of 33 nm. The morphology was visualized by scanning electron microscope/energy-dispersive X-ray analysis. The physicochemical properties were studied by the FTIR, XPS, and optical analyses. The diffuse reflectance gives a direct forbidden band of 3.26 eV. The electrochemical characterization showed an n-type semiconductor with a flat band of - 0.56 V_Ag/AgCl. The photodegradation of Cefixime (CFX) was carried out under solar light; the operating parameters such as the catalyst dose, solution pH, and initial CFX concentration (C_o) were optimized. The best performance occurs at neutral pH ~ 6 within 4 h with an abatement of 94% for an initial CFX concentration of 5 mg/L and MZO dose of 0.75 g/L. The photodegradation follows a first-order kinetic with an apparent rate constant of 0.012 min^-1. The effects of scavenging agents indicated the dominant role of hydroxyl ^•OH followed by the holes (h⁺). The results showed the potentiality of MZO as an environmentally friendly photocatalyst for CFX photodegradation.