An unprecedented fully reduced {Mo^V ₆₀} polyoxometalate: from an all-inorganic molecular light-absorber model to...

Fully reduced polyoxometalates are predicted to give rise to a broad and strong absorption spectrum, suitable energy levels, and unparalleled electronic and optical properties. However, they are not available to date. Here, an unprecedented fully reduced polyoxomolybdate cluster, namely Na₈[Mo^V ₆₀O₁₄₀(OH)₂₈]·19H₂O {Mo^V ₆₀}, was successfully designed and obtained under hydrothermal conditions, which is rare and is the largest fully reduced polyoxometalate reported so far. The Mo^V ₆₀ molecule describes one Keggin {ε-Mo₁₂} encapsulated in an unprecedented {Mo₂₄} cage, giving rise to a double truncated tetrahedron quasi-nesting architecture, which is further face-capped by another four {Mo₆} tripods. Its crystalline stability in air, solvent tolerance, and photosensitivity were all shown. As a cheap and robust molecular light-absorber model possessing wide light absorption, Mo^V ₆₀ was applied to build a co-sensitized solar cell photoelectronic device along with N719 dyes and the optimal power conversion efficiency was 28% higher than that of single-dye sensitization. These results show that Mo^V ₆₀ polyoxometalate could serve as an ideal model for the design and synthesis of all-inorganic molecular light-absorbers for other light-driven processes in the future.