Pollution characteristics and environmental availability of toxic elements in soil from an abandoned...

Understanding the pollution characteristics and assessing the ecological risk of toxic metals in mine soil are crucial to controlling and managing risks in abandoned mine areas. In this study, the profile soil pollution characteristics and modified ecological risk of As, Cd, Hg, Pb, Sb, and Tl for both the different mining functional areas and the downstream impacted areas at a large-scale abandoned arsenic-containing mine were studied. Results showed that both the profile soils at the mining functional areas and the surface layer in downstream sites are heavily polluted by As, Cd, Hg, Sb, and Tl. As, Hg, Sb, and Tl mainly accumulated on soils with a depth of 0-1.5 m. In contrast, these metals in the mining site were gradually increased with soil depth above the bedrock strata. Cd and Pb were mainly concentrated at depth of 2.5-3.5 m in the smelting with by-product processing site. The speciation of metals in the profile soils mainly occurred in residual fraction. However, high levels of potential mobile As and Sb were found in mining soils and smelting surface soils, as well as Tl in deep soils at mining functional sites and top soils at downstream sites, with their mean contents in these areas arrived to 2950 mg kg^-1, 9.64 mg kg^-1, and 0.98 mg kg^-1, respectively. In addition, the modified ecological risk assessment (NIRI_m) values revealed a substantial ecological risk of As, Cd, Hg, and Sb in both the entire profile soils at the mining, smelting sites and topsoil (0-1.5 m) at the adjacent downstream site. In summary, the pollution characteristics and potential ecological risk of toxic metals in profile soils from the different functional sites at arsenic-containing mine were significantly different and suitable control strategies for available toxic elements should be adopted in the different functional sites of mine.