Sources identification of ammonium in PM_2.5 during monsoon season in Dhaka, Bangladesh

Ammonia (NH₃) is taken up by fine particulate matter (PM_2.5), and there are concerns about its impact on the environment and health. The source of NH₃, which was thought to be of agricultural sources, has recently been suspected to be non-agricultural sources in urban areas. Here, we collected PM_2.5 during the monsoon season in Dhaka, Bangladesh, the most polluted city in the world, and analyzed the δ¹⁵N-NH₄⁺ in PM_2.5. As the result, the δ¹⁵N-NH₄⁺ ranged from 9.2 ‰ to 34.4 ‰ (average: 20.7 ± 4.8 ‰), the highest of any of the averaged values annual reported in previous researches. In order to perform source analysis, the NH₃ concentrations were estimated using the thermodynamic model ISORROPIA-II. The estimated concentration of NH₃ gas averaged 40.8 μg/m³ (3.0-154.6 μg/m³). The contributions calculated with the mixing model to the δ¹⁵N-NH₄⁺ values in PM_2.5 in Dhaka, Bangladesh averaged 25.3 ± 14 %, 22.8 ± 10 %, 26.5 ± 15 %, and 25.4 ± 10 % for waste, fertilizer, NH₃ slip, and fossil fuel combustion, respectively. Non-agricultural sources (NH₃ slip, and fossil fuel combustion) accounted for almost half (51.9 %) of the contributions. In addition, the several validation tests of the isotope mixing model were also performed. For validating the uncorrected and corrected source data for δ¹⁵N-NH₃, the contribution of non-agricultural sources with uncorrected source data would have been very high (>80 %), much higher than the corrected source data.