Enhanced thermal activation of persulfate by coupling hydrogen peroxide for efficient degradation of pyrene

In this study, H₂O₂ was introduced into thermally activated persulfate oxidation system (T-HPS), and the oxidation of pyrene (PYR) was investigated by the combined T-HPS technology. The results showed that H₂O₂ could significantly improve the reactivity of the thermally activated persulfate system (T-PS), with 240-min PYR degradation ratio increasing from 79.3% to 97.2% at 70 °C. In the T-HPS system, as persulfate initial concentration increased from 5 to 100 μM, the kinetic rate constant (k_obs) of PYR degradation increased from 4.70 × 10^-3 to 3.01 × 10^-2 min^-1, but the k_obs did not show a positive association with H₂O₂ concentration with the same range, and the highest k_obs was obtained at the H₂O₂ initial concentration of 20 μM. The optimal ratio of PS and H₂O₂ was set at 1:1 with the initial concentrations of the two oxidants both being 20 μM. Furthermore, PYR could be removed efficiently in a wide range of pH, and the best PYR degradation performance was obtained under neutral pH. Scavenging experiments demonstrated that OH played a more important role in PYR degradation in the T-HPS system than in the T-PS system. As suggested by the Arrhenius equation, the activation energy decreased from 124.5 to 107.4 kJ mol^-1 after adding H₂O₂ to the T-PS system. This study provides a new oxidation approach that could prompt the T-PS activity by adding a suitable dosage of H₂O₂.