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Measuring the Spin-Lattice Relaxation Magnetic Field Dependence of Hyperpolarized [1-13C]pyruvate
Published on: September 13, 2019
Slow magnetic relaxation in a Dy3 triangle and a bistriangular Dy6 cluster
Wen Wang1, Tao Shang2, Juan Wang1
1Department of Chemistry and Key Laboratory of Advanced Energy Materials Chemistry (MOE) and TKL of Metal and Molecule Based Material Chemistry, Nankai University, Tianjin 300071, China. maynk@nankai.edu.cn.
Abstract:
Two lanthanide single-molecule magnets (SMMs) [Dy3(μ3-OH)(HL-1)3(H2O)3](NO3)2·3H3O (1, H3L-1 = (E)-3-(((8-hydroxyquinolin-2-yl)methylene)amino)propane-1,2-diol) and [Dy6(μ3-OH)4(H2L-2)4(HL-2)2(L-2)2] (2, H3L-2 = (E)-2-hydroxy-N'-(2-hydroxy-3-methoxybenzylidene)benzohydrazide) were synthesized and characterized structurally and magnetically. Complex 1 contains a triangular Dy3 core in which the three Dy3+ ions share a μ3-OH- anion and the deprotonated ligands of (HL-1)2- serve both capping and bridging functions, while 2 displays a centrosymmetric hexanuclear DyIII structure with two similar Dy3 triangular cores ligated by two fully deprotonated (L-2)3- ligands, each of which shares two μ3-OH- anions. All the DyIII ions are eight-coordinated with quasi D2d or C2v symmetry. Magnetic studies reveal that 1 exhibited two-step magnetic relaxation under an applied dc field of 800 Oe, with effective energy barriers of 40.1 and 31.0 K for the slow relaxation (SR) and fast relaxation regimes (FR), respectively. Meanwhile, 2 only showed a tail of slow magnetic relaxation at above 2 K. Ab initio calculations have been carried out to show the nature of their different magnetic properties.
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