Porous Pd-Sn Alloy Nanotube-Based Chemiresistor for Highly Stable and Sensitive H₂ Detection

While H₂ is indispensable as a green fuel source, it is highly flammable and explosive. Because it is difficult to detect due to its lack of odor and color, a solution for proper monitoring of H₂ leakage is essential to ensure safe handling. To this end, we have successfully fabricated hollow Pd-Sn alloy nanotubes (NTs) with a Brunauer-Emmett-Teller surface area of 223.0 m²/g through electrospinning and a subsequent etching method, which is the first demonstration of synthesizing Pd-based hollow alloy nanofibers with ultrafine grain sizes. We found that the alloying of Pd with Sn could effectively prevent degradation of the sensing performance upon the α-β phase transition during hydrogen detection. Besides, the highly porous structure with smaller nanograins offered more exposed active sites and higher gas accessibility to bulk materials. The resultant Pd-Sn NTs exhibited excellent sensitivity toward H₂ (0.00005-3%). Notably, the limit of detection of 0.0001% is an outstanding achievement on H₂ sensing among state-of-the-art H₂ sensors. Moreover, when exposed to a high concentration of H₂ (3%), Pd-Sn NTs showed excellent cycling stability with a standard deviation of 0.07% and a sensitivity of 9.27%. These obtained sensing results indicate that Pd-Sn NTs can be used as a highly sensitive and stable H₂ gas sensor at room temperature (25 °C).