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Updated: Sep 20, 2025

Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
Published on: June 7, 2018
Observation of the Specific Heat Jump in the Se-Substituted MoTe2 Single Crystals
Aoi Kobayashi1, Yoshiki Takano1, Satoshi Demura1
1College of Science and Technology, Nihon University, Chiyoda-ku, Tokyo 101-8308, Japan.
Abstract:
1T'-MoTe2 has gained considerable attention owing to its topological character. This material undergoes spatial inversion symmetry at 300 K. A structural transition to the Td phase, which is represented by a kink in the resistivity, was observed below 250 K without inversion symmetry along the c-axis, while superconductivity was observed at 0.1 K. Substitution of Se into this material suppressed the appearance of the kink structure and increased the superconducting transition temperature to 2 K, which is consistent with previously reported results on polycrystalline samples. However, a specific heat jump was observed in the obtained single crystals, which did not exhibit kink structures in their resistivity. The results suggest that the Td structure was not suppressed entirely after Se substitution and that superconductivity was achieved without inversion symmetry.
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