Feasibility Study on the Fused Filaments of Injection-Molding-Grade Poly(Ethylene Terephthalate) for 3D Printing

Unlike that of glycol-modified Poly(ethylene terephthalate) (PETG), the crystallinity of PET can be post-adjusted to enhance the mechanical properties of 3D-printed parts such as food-contact tableware and bio-implants. The aforementioned PET material could be 3D printed to produce the desired parts for performance evaluation before mass production by injection molding. In this study, using differential scanning calorimetry (DSC), we examined the pellets, extruded filament, and printed specimen to identify variations in melting and crystalline temperatures, as well as crystallinity. It was also shown by Thermogravimetric Analyzer (TGA) that the addition of talcum powder increased the thermal stability of filament and resulted in an interaction between the fillers and polymer matrix. The crystallinities of the filament and printed specimen were then compared with the yield strengths and Young's moduli to confirm the effects of the decreased molecular weight of the extruded PET filament. The talcum powder effectively improved the viscosity of the PET melted during the extrusion process for the filament and then enhanced the crystallinity of the PET, thereby achieving a significantly higher Young's modulus. The printed PET specimen presented an excellent yield strength of 25 MPa and ductile properties with strain-at-break values of 30%, successfully indicating potential applications in food-contact tableware and bio-implants.