Photocatalytic C(sp3) radical generation via C-H, C-C, and C-X bond cleavage
Chia-Yu Huang1, Jianbin Li1, Chao-Jun Li1
1Department of Chemistry, FRQNT Centre for Green Chemistry and Catalysis, McGill University 801 Sherbrooke Street W. Montreal Quebec H3A 0B8 Canada cj.li@mcgill.ca.
Abstract:
C(sp3) radicals (R˙) are of broad research interest and synthetic utility. This review collects some of the most recent advancements in photocatalytic R˙ generation and highlights representative examples in this field. Based on the key bond cleavages that generate R˙, these contributions are divided into C-H, C-C, and C-X bond cleavages. A general mechanistic scenario and key R˙-forming steps are presented and discussed in each section.
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