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Updated: Sep 8, 2025

Microscopic Visualization of Porous Nanographenes Synthesized through a Combination of Solution and On-Surface Chemistry
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Microscopic Visualization of Porous Nanographenes Synthesized through a Combination of Solution and On-Surface Chemistry

Published on: March 4, 2021

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A sequential cyclization/π-extension strategy for modular construction of nanographenes enabled by stannole

Harrison M Bergman1, D Dawson Beattie1, Gavin R Kiel1

  • 1Department of Chemistry, University of California Berkeley California 94720 USA tdtilley@berkeley.edu.

Chemical Science
|June 13, 2022
PubMed
Summary

This study introduces stannoles as stable diene equivalents for synthesizing polycyclic aromatic hydrocarbons (PAHs). This novel approach overcomes limitations in current Diels-Alder reactions, enabling efficient π-extension for larger PAH structures.

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