High-efficient mineralization of formaldehyde by three-dimensional "PIZZA"-like bismuth molybdate-titania/diatomite...

The application of TiO₂-based photocatalysts in air pollution control has attracted much attention thanks to their advantageous green and sustainable performance. However, how to improve the degradation efficiency under visible light is still challenging. Herein, we report a ternary three-dimensional "PIZZA"-like Bi₂MoO₆-TiO₂/diatomite (BTD) composite with high-efficient mineralization and recycling performance towards gaseous formaldehyde (HCHO) under visible light. The high-efficient adsorption-photocatalysis collaborative system with intimate interface combination is successfully established among Bi₂MoO₆ (BMO), TiO₂ and diatomite. The HCHO mineralization rate constant of BTD-1:2 composite is up to around 4.03 times and 2.18 times higher than those of bare BMO and binary Bi₂MoO₆-TiO₂ composite, respectively. It is indicated that the introduction of diatomite increases active sites and plays the vital role in the improvement of photocatalysis. In addition, the photogenerated holes (h⁺) and hydroxyl radical (OH) are proved to be the main active species for HCHO mineralization. Furthermore, there is a competitive adsorption relationship between water (H₂O) molecules and HCHO molecules, and both H₂O molecules and oxygen (O₂) molecules participated in the reaction of HCHO mineralization based on in-situ DRIFTs spectra analysis. Our work would give a new perspective on gaseous HCHO purification.