Recent developments in MOF and MOF based composite as potential adsorbents for removal of aqueous environmental contaminants

With the growth of globalization which has been the primary cause of water pollution, it is utmost necessary for us living being to have access to clean water for the purpose of drinking, washing and various other useful applications. With the purpose of future security and to restore our ecological balance, it is essential to give much significance towards the removal of unwanted toxic contaminants from our water resources. In this regard adsorptive removal of toxic pollutants from wastewater with porous adsorbent is regarded as one of the most promising way for water decontamination process. Metal organic frameworks (MOFs) comprising of uniformly arranged pores, abundant active sites and containing an easily tunable structure has aroused as a promising material for adsorbent to remove the unwanted contaminants from water sources. The adsorption of pollutants by the different MOFs surface are driven by various interactions including π-π, acid-base, electrostatic and H-bonding etc. On the other hand, the removal of various contaminants by MOFs is influenced by various factors including pH, temperature and initial concentration. In this review we will specifically discuss the adsorptive removal of different organic and inorganic pollutants present in our water systems with the use of MOFs as adsorbent along with the various factors and interaction mechanism manipulating the adsorption behaviour.