Morphological characteristics of calcium carbonate crystallization in CO₂ pre-cured aerated concrete

Early-stage CO₂ curing technology for alkaline construction materials (such as cement concrete) has gained increasing interest owing to the advantages of material properties improvement and high potential of CO₂ sinking. Less attention, however, has been paid to morphological characteristics of CaCO₃ in carbonated cement concrete. The crystal structure and micromorphology of CaCO₃ in an early-age aerated concrete (AC) cured under CO₂ gas pressures of 0.1, 1, and 2 bar were investigated. The fabricated AC has a high CO₂ sorption capacity (∼35 g CO₂ per 100 g cement in a 100 mm cube). The morphological characteristics of CaCO₃ were statistically analyzed in terms of long-axis length (b), short-axis length (a), and aspect ratio (K = b/a). As CO₂ pressure increases, b is almost unchanged from 0.8-1.8 μm, a decreases from 0.7 to 0.4 μm, and, consequently, K increases from 1.3 to 2.5. The different CaCO₃ crystal morphologies in AC are ascribed to the CO₂ pressure-associated crystal transformation processes: low gas pressure induces a symmetric CaCO₃ growth, while high gas pressure causes a faster calcite growth at the crystal tip ends. The findings would deepen the understanding of CaCO₃ crystal formation under different CO₂ curing pressures for tuning the microstructure of CO₂-cured cement concrete.