Characterization of synthetic turf rubber granule infill in Japan: Rubber additives and related compounds

We have conducted several studies with an overall goal of assessing the effects of rubber granules in synthetic turf on the health of athletes, other players, and children in Japan. As part of these studies, the investigation reported herein was aimed at analyzing the concentrations of rubber additives (vulcanization accelerators, antioxidants, and cross-linking agents) and related chemicals in 46 rubber infills prior to their use in synthetic turf fields in Japan. Of the 36 chemicals selected for targeted analysis, 26 were detected and quantified. Nontargeted analyses further identified and quantified 16 compounds derived from vulcanization accelerators, plasticizers, and other additives. The types and concentrations of the detected compounds varied both between products and within the same product; in the case of rubber infill products made from recycled rubber, this variation was caused by the different types of rubber products recycled as raw materials. Elution tests with four simulated biofluids (gastric juice, intestinal juice, saliva, and perspiration) revealed that the elution rates varied between compounds and were affected by the presence of coatings. Most compounds had low elution rates in all the simulated biofluids, with many at or below the limit of quantification. The data reported herein will be utilized in the risk characterization part of our subsequent study on the health risk assessment of rubber infill.