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Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
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Temperature induced phase transformation in Co.

R Sewak1,2, C C Dey3,4, D Toprek5

  • 1Saha Institute of Nuclear Physics, 1/AF Bidhannagar, Kolkata, 700064, India.

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|June 16, 2022
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This summary is machine-generated.

Cobalt

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Area of Science:

  • Materials Science
  • Condensed Matter Physics

Background:

  • The phase transformation behavior of cobalt (Co) between hexagonal close-packed (hcp) and face-centered cubic (fcc) phases is crucial for understanding its magnetic and structural properties.
  • Previous studies reported conflicting data regarding the temperature-dependent stability of hcp and fcc cobalt phases.

Purpose of the Study:

  • To investigate the temperature-dependent phase transformation behavior of cobalt.
  • To re-examine the stability ranges of hcp and fcc cobalt phases.
  • To provide new theoretical interpretations for cobalt phase transformations.

Main Methods:

  • Perturbed angular correlation (PAC) measurements were employed to study cobalt phase transformations.
  • Density functional theory (DFT) calculations using the full potential (linearized) augmented plane wave (FP-LAPW) method were performed.
  • Hyperfine magnetic fields at Ta impurity atoms were calculated and compared with experimental data.

Main Results:

  • The hcp phase of cobalt was found to be predominant at both low temperatures (298 K) and high temperatures (973 K).
  • The fcc phase was stabilized around 500 K, contradicting earlier findings.
  • Experimental hyperfine magnetic fields for hcp and fcc Co at room temperature were measured to be 18.7(6) T and 12.8(3) T, respectively.
  • DFT calculations corroborated the experimental findings for hyperfine magnetic fields in both hcp and fcc cobalt phases.

Conclusions:

  • The study reveals a revised understanding of temperature-dependent phase stability in cobalt, with hcp stabilization at both low and high temperatures.
  • Experimental results challenge previous models of cobalt phase transformation, necessitating new theoretical interpretations.
  • The agreement between experimental PAC measurements and DFT calculations validates the revised understanding of magnetic properties in different cobalt phases.