Long-term trend in surface ozone in Houston-Galveston-Brazoria: Sectoral contributions based on changes in volatile...

This study investigated the long-term variations in ambient levels of surface ozone, volatile organic compounds (VOCs), and nitrogen oxides (NO_x) within the Houston-Galveston-Brazoria (HGB) region. Analysis of ozone levels revealed an overall reduction in the maximum daily 8-h average ozone (MDA8 O₃) from 2000 to 2019 (April-October) with an average rate of ∼ -0.48 ppb/yr across HGB. With a few exceptions, the MDA8 O₃ reduction rates were more pronounced for the monitoring sites closer to the Houston Ship Channel (HSC). Meanwhile, ambient levels of NO_x and most VOC species (across the three representative sites as Houston Bayland Park, Haden Road, and Lynchburg Ferry) decreased significantly within the same investigation period, reflecting the impact of emission reductions. The positive matrix factorization (PMF) model applied to the mentioned sites identified regional background ozone, petrochemical emissions, engine combustion, natural gas/fuel evaporation, and solvent/painting/rubber industries as the major sources of MDA8 O₃. The regional background ozone was the predominant source, accounting for 59-70% of MDA8 O₃ across the three sites. Regarding the local anthropogenic emissions, natural gas/fuel evaporation was the largest contributor (19.5 ± 6.1%) to MDA8 O₃ at Houston Bayland Park, whereas petrochemical facilities (10.9 ± 4.9%) and solvent/painting/rubber industries (18.1 ± 9.5%) were the largest factor at Haden Road and Lynchburg Ferry, respectively. Notable reductions were found in the contributions of petrochemical emissions, engine combustion, and natural gas/fuel evaporation to MDA8 O₃ within 2000-2019, but an increasing trend was revealed in the role of solvent/painting/rubber industries on MDA8 O₃ most probably due to the enhanced demand for their products. Results of this study corroborated the success of emission control policies in limiting ozone precursors and provided useful details for prioritizing emission reduction policies to further reduce ozone pollution in the HGB.