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Updated: Sep 7, 2025

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Oxygen Vacancy-Induced Construction of CoO/h-TiO2 Z-Scheme Heterostructures for Enhanced Photocatalytic Hydrogen
Xiaoyu Chen1, Bojing Sun1, Jiayu Chu2
1MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China.
Abstract:
Environmentally friendly catalysts with excellent performance and low cost are critical for photocatalysis. Herein, using hydrogenated TiO2 (h-TiO2) nanosheets with enriched oxygen vacancies as the support, two-dimensional CoO/h-TiO2 Z-scheme heterostructures are fabricated for hydrogen production through photocatalytic water splitting. It is revealed that the oxygen vacancies in h-TiO2 can inhibit the oxidation of Co2+ into high-valence Co3+ during the hydrothermal reaction and thermal treatment processes. A CoO/h-TiO2 Z-scheme heterostructure possesses a space charge region and a built-in electric field at the interface, and oxygen vacancies in h-TiO2 can provide more reactive sites, which synergistically improve the separation and transportation of photogenerated carriers. As a result, the photocatalytic hydrogen evolution rate achieves 129.75 μmol·h-1 (with 50 mg of photocatalysts) on the optimized CoO/h-TiO2 heterostructures. This work provides a new design idea for the preparation of excellent TiO2-based photocatalysts.
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